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Structure Formation In Solution
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Structure Formation In Solution - neues Buch

ISBN: 9783540252719

ID: 19229801

1. 1 Macroionic Systems and the Scope of the Book Inthepresentmonograph, wewilldiscussionicpolymersolutionsandcolloidal dispersions. When these substances are dissolved into a solvent, they produce ionicspecies havinglargemolecularweightsandtheir counterions. We knowa variety of naturally occurring ionic polymers and chemically synthesizedc- pounds. Examples of the former are nucleic acids and. 1. 1 Macroionic Systems and the Scope of the Book Inthepresentmonograph, wewilldiscussionicpolymersolutionsandcolloidal dispersions. When these substances are dissolved into a solvent, they produce ionicspecies havinglargemolecularweightsandtheir counterions. We knowa variety of naturally occurring ionic polymers and chemically synthesizedc- pounds. Examples of the former are nucleic acids and some proteins, which playanimportantroleinbiologicalsystems. Examplesofsyntheticionicpo- mers are polyacrylic acid (PAA), polystyrenesulfonic acid (PSS) and poly- lylamine (PAAm). PAAisahighpolymer, inwhichmacrylicacidmoleculesCH =CH(COOH) 2 arelinearlypolymerizedby covalent bonds. Thenumber mis calledthe degree 3 of polymerization and is usually of the order of 10. When PAA is dissolved in a dissociating solvent like water, anionic macroions and counterions are produced. In the following scheme, the counterions are protons but they may + be metal cations such as Na: ?CH? CH CH? CH? 2 2 + / ? / + mH? COOH COO m m PAA PAA anion Counterions. PAAm is a cationic polymer and dissociates into PAAm cations and anionic counterions as shown below: ?CH? CH CH? CH? 2 2? / +mHCl? / +mCl + CH? NH CH? NH 2 2 2 3 m m PAAm PAAm cation Counterions. 2 1 Introduction + ? In the case of NaCl, it dissociates into Na and Cl, which both have low molecular weights. On the other hand, PAA anions and PAAm cations have 3 highmolecularweights. Ifmis10, onepolymerion(macroion)hasananalyt- 3 + icalchargenumberZ of10, whichisexceedinglylargerthan1forNa. Books, Science and Geography~~Chemistry~~Physical Chemistry, Structure Formation In Solution~~Book~~9783540252719~~Norio Ise, Ikuo Sogami, , , , , , , , , ,, [PU: Springer, Berlin/Heidelberg]

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Structure Formation in Solution - Norio Ise
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Norio Ise:

Structure Formation in Solution - neues Buch

2005, ISBN: 3540252711

ID: 9814409740

[EAN: 9783540252719], Neubuch, [PU: Springer Jul 2005], POLYMERISATION ( POLYMERE ); - POLYMERISATION; STRUKTUR (PHYSIKALISCH, CHEMISCH), This item is printed on demand - Print on Demand Titel. Neuware - 1. 1 Macroionic Systems and the Scope of the Book Inthepresentmonograph,wewilldiscussionicpolymersolutionsandcolloidal dispersions. When these substances are dissolved into a solvent, they produce ionicspecies havinglargemolecularweightsandtheir counterions. We knowa variety of naturally occurring ionic polymers and chemically synthesizedc- pounds. Examples of the former are nucleic acids and some proteins, which playanimportantroleinbiologicalsystems. Examplesofsyntheticionicpo- mers are polyacrylic acid (PAA), polystyrenesulfonic acid (PSS) and poly- lylamine (PAAm). PAAisahighpolymer,inwhichmacrylicacidmoleculesCH =CH(COOH) 2 arelinearlypolymerizedby covalent bonds. Thenumber mis calledthe degree 3 of polymerization and is usually of the order of 10 . When PAA is dissolved in a dissociating solvent like water, anionic macroions and counterions are produced. In the following scheme, the counterions are protons but they may + be metal cations such as Na : CH CH CH CH 2 2 + + mH COOH COO m m PAA PAA anion Counterions. PAAm is a cationic polymer and dissociates into PAAm cations and anionic counterions as shown below: CH CH CH CH 2 2 +mHCl +mCl + CH NH CH NH 2 2 2 3 m m PAAm PAAm cation Counterions. 2 1 Introduction + In the case of NaCl, it dissociates into Na and Cl , which both have low molecular weights. On the other hand, PAA anions and PAAm cations have 3 highmolecularweights. Ifmis10 ,onepolymerion(macroion)hasananalyt- 3 + icalchargenumberZ of10 ,whichisexceedinglylargerthan1forNa . 350 pp. Englisch

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Structure Formation in Solution: Ionic Polymers and Colloidal Particles - Ise, Norio, Sogami, Ikuo
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Ise, Norio, Sogami, Ikuo:
Structure Formation in Solution: Ionic Polymers and Colloidal Particles - Taschenbuch

2004

ISBN: 9783540252719

Gebundene Ausgabe, ID: 274092848

New York: Wiley-VCH, 2004. Book. Near Fine Ex-Library Cond.. Hardcover. 8vo - over 7¾" - 9¾" tall. 393 pgs. Covers: anionic polymerization; cationic polymerization; related processes including synthesis, mechanistic studies, and applications. Yellow boards show usual library markings. Very clean and tightly bound.., Wiley-VCH, 2004, Chemical Industry Press Pub. Date :1999-04-01. paperback. New. Ship out in 2 business day, And Fast shipping, Free Tracking number will be provided after the shipment.Paperback. Pages Number: 228 Language: Chinese. Publisher: Chemical Industry Press Pub. Date :1999-04-01. This book is a college English reading materials. Book of 32 lessons divided into three parts. The first part is the polymer chemistry and physics to explain the basis of the polymer chain. and gradually. ionic polymerization. and rheological properties of polymer solution. polymer aggregation structure. etc.; the second part of Polymer Reaction Engineering. described suspension. emulsion... Satisfaction guaranteed,or money back., Chemical Industry Press Pub. Date :1999-04-01, Springer. Used - Like New. Book in almost Brand New condition. 100% Money Back Guarantee. Shipped to over one million happy customers. Your purchase benefits world literacy!, Springer

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Structure Formation in Solution. - Ise, Norio; Ikuo S. Sogami
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[EAN: 9783540252719], [PU: Berlin, Springer, 2005.], Science|Life Sciences|Biochemistry, Technology|Textiles & Polymers, Ionic Polymers and Colloidal Particles. XXI, 350 p. Hardcover. Gestempelt.

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ISBN: 9783540252719

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Structure Formation in Solution Ionic Polymers and Colloidal Particles
Autor:

Ise, Norio; Sogami, Ikuo

Titel:

Structure Formation in Solution Ionic Polymers and Colloidal Particles

ISBN-Nummer:

9783540252719

This book is designed to critically review experimental findings on ionic polymers and colloidal particles and to prove a theoretical framework based on the Poisson-Boltzmann approach. Structure formation in ionic polymer solutions has attracted attention since the days of H. Staudinger and J. D. Bernal. An independent study on ionic colloidal dispersions with microscopy provided a compelling evidence of structure formation. Recent technical developments have made it possible to accumulate relevant information for both ionic polymers and colloidal particles in dilute systems. The outstanding phenomenon experimentally found is microscopic inhomogeneity in the solute distribution in macroscopically homogeneous systems.To account for the observation, the present authors have invoked the existence of the counterion-mediated attraction between similarly charged solute species, in addition to the widely accepted electrostatic repulsion.

Detailangaben zum Buch - Structure Formation in Solution Ionic Polymers and Colloidal Particles


EAN (ISBN-13): 9783540252719
ISBN (ISBN-10): 3540252711
Gebundene Ausgabe
Taschenbuch
Erscheinungsjahr: 2005
Herausgeber: Springer-Verlag GmbH
350 Seiten
Gewicht: 0,774 kg
Sprache: eng/Englisch

Buch in der Datenbank seit 02.06.2007 23:42:32
Buch zuletzt gefunden am 03.07.2015 12:26:48
ISBN/EAN: 9783540252719

ISBN - alternative Schreibweisen:
3-540-25271-1, 978-3-540-25271-9

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